New Paper: Heavily Substituted Atropisomeric Diarylamines by Unactivated Smiles Rearrangement of N‐Aryl Anthranilamides
Posted: September 7, 2017 Filed under: Alumni, Collaborators, Papers Comments Off on New Paper: Heavily Substituted Atropisomeric Diarylamines by Unactivated Smiles Rearrangement of N‐Aryl AnthranilamidesWhat UG summer student Harvey Dale did last summer (2016)… worked out a likely mechanism to explain experimental observations:
Diarylamines find use as metal ligands and as structural components of drug molecules, and are commonly made by metal‐catalyzed C−N coupling. However, the limited tolerance to steric hindrance of these…